164229-01-0

Basic information

• Product Name: Toluene-4-sulfonic acid (S)-2,6-dimethyl-hept-5-enyl ester
• Synonyms: Toluene-4-sulfonic acid (S)-2,6-dimethyl-hept-5-enyl ester
• CAS NO: 164229-01-0
• Molecular Weight: 296.431
• Mol File: 164229-01-0.mol

Chemical Properties

• CAS DataBase Reference: Toluene-4-sulfonic acid (S)-2,6-dimethyl-hept-5-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-sulfonic acid (S)-2,6-dimethyl-hept-5-enyl ester(164229-01-0)
• EPA Substance Registry System: Toluene-4-sulfonic acid (S)-2,6-dimethyl-hept-5-enyl ester(164229-01-0)

Safety Data

• Hazardous Substances Data: 164229-01-0(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 161512-73-8 (2S)-2,6-dimethyl-5-hepten-1-ol 

Downstream Products

• 164228-94-8 [(2R,5S)-1-((1R,2R,3S,5S)-3-Benzyloxymethyl-5-hydroxy-2-methyl-cyclopentylmethyl)-5-methyl-piperidin-2-yl]-acetic acid ethyl ester 
• 164229-04-3 (2S,3S,3aS,6S,8aR,9S,9aR)-2-Benzyloxymethyl-3,6-dimethyl-9-phenylsulfanylmethyl-dodecahydro-4a-aza-cyclopenta[b]naphthalene 
• 164228-95-9 (2S,3S,3aS,6S,8aR,9S,9aR)-2-Benzyloxymethyl-3,6-dimethyl-dodecahydro-4a-aza-cyclopenta[b]naphthalene-9-carboxylic acid ethyl ester 
• 164229-03-2 ((2S,3S,3aS,6S,8aR,9S,9aR)-2-Benzyloxymethyl-3,6-dimethyl-dodecahydro-4a-aza-cyclopenta[b]naphthalen-9-yl)-methanol 

Relevant articles and documents

Highly diastereoselective cyclopentane construction: Enantioselective synthesis of the dendrobatid alkaloid 251F

We report the first total synthesis, and thus structural confirmation, of the dendrobatid alkaloid 251F (1), based on the retrosynthetic analysis illustrated (1 → → 4). Key observations in this synthesis are that both the Rh-mediated cyclization of 4 and