16433-97-9

Basic information

• Product Name: (2-propen-2-yl)diphenylphosphane
• Synonyms: (2-propen-2-yl)diphenylphosphane
• CAS NO: 16433-97-9
• Molecular Weight: 226.258
• Mol File: 16433-97-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2-propen-2-yl)diphenylphosphane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-propen-2-yl)diphenylphosphane(16433-97-9)
• EPA Substance Registry System: (2-propen-2-yl)diphenylphosphane(16433-97-9)

Safety Data

• Hazardous Substances Data: 16433-97-9(Hazardous Substances Data)

Upstream product

• 61835-96-9 acetone-2,4,6-tri-isopropylbenzenesulphonylhydrazone 
• 1079-66-9 chloro-diphenylphosphine 
• 557-93-7 2-bromoprop-1-ene 
• 1213-51-0 (trimethylstannyl)diphenylphosphine 

Downstream Products

• 125708-46-5 (β-trimethylstannyl)CH2CH(methyl)diphenylphosphine 
• 4569-34-0 Diphenyl(1-methylvinyl)-phosphine oxide 
• 37518-40-4 5-methyl-3-(4-nitro-phenyl)-1,4,4-triphenyl-1,4,5,6-tetrahydro-[1,2,4]diazaphosphininium; chloride 
• 37518-39-1 5-methyl-1,3,4,4-tetraphenyl-1,4,5,6-tetrahydro-[1,2,4]diazaphosphininium; chloride 

Relevant articles and documents

Homolytic substitution at phosphorus for the synthesis of alkyl and aryl phosphanes

(Chemical Equation Presented) A transition-metal-free radical phosphonation using Me3SnPPh2 and the less toxic Me 3SiPPh2 is reported. These readily available reagents react highly efficiently with primary and secondary alkyl radicals. Moreover, aryl radicals and tertiary alkyl radicals are phosphonated with Me 3SnPPh2 (see scheme; R = aryl, alkyl, vinyl; X = 1, Br, OC(S)imidazolyl). DFT calculations provide insights into the mechanism of the reaction.

ENEPHOSPHINILATION

A general method is described for the formation of vinylphosphines from arylsulfonylhydrazones.Oxidation of the resulting vinylphosphines yields phosphine oxides.