1643685-75-9

Upstream product

• 1643685-69-1 (4S,6R)-6-[(ethenesulfonyl)oxy]nona-1,8-dien-4-yl (E)-but-2-enoate 
• 1643685-72-6 (S)-6-{[(R)-2,2-dioxo-5,6-dihydro-1,2-oxathiin-6-yl]methyl}-5,6-dihydro-2H-pyran-2-one 
• 768-33-2 phenyldimethylsilyl chloride 
• 136030-29-0 (2S,4S)-1,5-dichloro-2,4-pentanediol 
• 109905-51-3 (2S,4S)-1,2:4,5-dianhydro-3-deoxypentitol 
• 40630-12-4 1,5-dichloropentane-2,4-dione 
• 1643685-65-7 (4S,6R)-6-hydroxynona-1,8-dien-4-yl (E)-but-2-enoate 

Downstream Products

• 1643685-76-0 (4R,6R)-4-(dimethylphenylsilyl)-6-[(R)-2-hydroxypent-4-en-1-yl]-3,4,5,6-tetrahydro-2H-pyran-2-one 
• 1643685-77-1 (4S,6S)-4-{[(4R,4R)-4-(dimethylphenylsilyl)-6-oxo-3,4,5,6-tetrahydro-2H-pyran-2-yl]methyl}-6-(iodomethyl)-1,3-dioxan-2-one 
• 1643685-78-2 tert-butyl {(R)-1-[(2R,4R)-4-(dimethylphenylsilyl)-6-oxo-3,4,5,6-tetrahydro-2H-pyran-2-yl]pent-4-en-2-yl}carbonate 
• 1643685-79-3 (4R,6R)-4-(dimethylphenylsilyl)-6-{[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-3,4,5,6-tetrahydro-2H-pyran-2-one 
• 1643685-80-6 (4R,6R)-4-(dimethylphenylsilyl)-6-{[(4S,6S)-6-(iodomethyl)-2,2-dimethyl-1,3-dioxan-4-yl]methyl}-3,4,5,6-tetrahydro-2H-pyran-2-one 
• 1643685-81-7 (3R,4R,6R)-4-(dimethylphenylsilyl)-6-{[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-3-[(S)-1-hydroxyhexyl]-3,4,5,6-tetrahydro-2H-pyran-2-one 
• 1643685-82-8 (S)-1-{(3R,4R,6R)-4-(dimethylphenylsilyl)-6-{[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-2-methoxy-3,4,5,6-tetrahydro-2H-pyran-3-yl}hexan-1-ol 
• 1643685-83-9 C₃₃H₅₀O₅SSi 
• 1643685-84-0 (3S,4R,6S)-6-{[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-3-[(S)-1-hydroxyhexyl]-2-methoxytetrahydro-2H-pyran-4-ol 
• 1643685-85-1 tert-butyl [((S)-1-{(3S,4R,6R)-4-(tert-butyldimethylsilyloxy)-6-[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-2-methoxy-3,4,5,6-tetrahydro-2H-pyran-3-yl)hexyloxy]dimethylsilane 

Relevant academic research and scientific papers

Stereocontrolled synthesis of a C1-C10 building block ("Southwestern Moiety") for the unnatural enantiomers of the polyene polyol antibiotics filipin III and pentamycin: A sultone-forming ring-closing metathesis for protection of hom

In C2-symmetric diol 10 one OH group was substituted by crotonic acid and the other was incorporated in an ethenesulfonate. A twofold ring-closing metathesis under forcing conditions provided unsaturated lactone/unsaturated sultone 24. Conjugat