1643867-97-3

Upstream product

• 111219-94-4 Hex-5-enylidene-triphenyl-λ⁵-phosphane 
• 303044-46-4 (-)-(2R,3R,5R)-5-(tert-butyldiphenylsilyloxy)-2,3-(oxiranyl)-hexan-1-al 

Downstream Products

• 1643867-95-1 (R)-1-{(2R,3R)-3-[(Z)-hepta-1,6-dien-1-yl]oxiran-2-yl}propan-2-yl 4-acetoxy-2-{(3E,5E)-2-[(tert-butyldimethylsilyl)oxy]hepta-3,5-dien-1-yl}-6-hydroxybenzoate 
• 1622322-40-0 5-{(3E,5E)-2-[(tert-butyldimethylsilyl)oxy]hepta-3,5-dien-1-yl}-4-{[(R)-1-{(2R,3R)-3-[(Z)-hepta-1,6-dien-1-yl]oxiran-2-yl}propan-2-yloxy]carbonyl}-1,3-phenylene diacetate 

Relevant academic research and scientific papers

Synthetic studies towards radicicol through biomimetic macrolactonization and transannular aromatization reactions

Studies towards the total synthesis of the natural product radicicol are described that employ a late-stage esterification and aromatization by trapping a ketene intermediate. The subsequent biomimetic aromatization of the resultant triketo ester gave hig