1644030-61-4

Basic information

• Product Name: dimethyl 2-[5-methyl-5-(4-nitrophenyl)-2-phenylsulfonylhexa-2,3-dienyl]-2-(prop-2-ynyl)malonate
• CAS NO: 1644030-61-4
• Molecular Weight: 525.579
• Mol File: 1644030-61-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl 2-[5-methyl-5-(4-nitrophenyl)-2-phenylsulfonylhexa-2,3-dienyl]-2-(prop-2-ynyl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2-[5-methyl-5-(4-nitrophenyl)-2-phenylsulfonylhexa-2,3-dienyl]-2-(prop-2-ynyl)malonate(1644030-61-4)
• EPA Substance Registry System: dimethyl 2-[5-methyl-5-(4-nitrophenyl)-2-phenylsulfonylhexa-2,3-dienyl]-2-(prop-2-ynyl)malonate(1644030-61-4)

Safety Data

• Hazardous Substances Data: 1644030-61-4(Hazardous Substances Data)

Upstream product

• 63104-44-9 dimethyl 2,2-di(prop-2-ynyl)malonate 
• 1644031-12-8 dimethyl 2-[4-hydroxy-5-methyl-5-(4-nitrophenyl)hex-2-ynyl]-2-(prop-2-ynyl)malonate 
• 453562-77-1 2-methyl-2-(4-nitrophenyl)propionaldehyde 

Downstream Products

• 1644030-71-6 5,5-bis(methoxycarbonyl)-10,10-dimethyl-14-nitro-7-phenylsulfonyltricyclo[9.4.0.0^3,8]pentadeca-1⁽¹¹⁾,2,7,12,14-pentaene 

Relevant articles and documents

Rhodium(I)-catalyzed cycloisomerization of benzylallene-alkynes through C-H activation

The efficient RhI-catalyzed cycloisomerization of benzylallene-alkynes produced the tricyclo[9.4.0.03,8] pentadecapentaene skeleton through a C sp 2-H bond activation in good yields. A plausible reaction mechanism proceeds via oxidative addition of the acetylenic C-H bond to RhI, an ene-type cyclization to the vinylidenecarbene- RhI intermediate, and an electrophilic aromatic substitution with the vinylidenecarbene species. It was proposed based on deuteration and competition experiments.