1644119-79-8

Basic information

• Product Name: 2-bromo-5-(t-butyl)-1,3-bis(dibromomethyl)benzene
• Synonyms: 2-bromo-5-(t-butyl)-1,3-bis(dibromomethyl)benzene
• CAS NO: 1644119-79-8
• Molecular Weight: 556.755
• Mol File: 1644119-79-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-bromo-5-(t-butyl)-1,3-bis(dibromomethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-5-(t-butyl)-1,3-bis(dibromomethyl)benzene(1644119-79-8)
• EPA Substance Registry System: 2-bromo-5-(t-butyl)-1,3-bis(dibromomethyl)benzene(1644119-79-8)

Safety Data

• Hazardous Substances Data: 1644119-79-8(Hazardous Substances Data)

Upstream product

• 5345-05-1 4-t-butyl-2,6-dimethylbromobenzene 

Downstream Products

• 1609376-04-6 2-bromo-5-(t-butyl)-1,3-bis[bis(trimethylsilyl)methyl]benzene 

Relevant articles and documents

Syntheses and structures of terminal arylalumylene complexes

Terminal arylalumylene complexes of platinum [Ar-Al-Pt(PCy 3)2] (Ar=2,6-[CH(SiMe3)2] 2C6H3 (Bbp) or 2,6-[CH(SiMe3) 2]2-4-(tBu)C6H2 (Tbb)) have been synthesized either by the reaction of a dialumene-benzene adduct with [Pt(PCy3)2], or by the reduction of 1,2-dibromodialumanes Ar(Br)Al-Al(Br)Ar in the presence of [Pt(PCy3)2]. X-Ray crystallographic analysis reveals that the Al-Pt bond lengths of these arylalumylene complexes are shorter than the previously reported shortest Al-Pt distance. DFT calculations suggest that the Al-Pt bonds in the arylalumylene complexes have a significantly high electrostatic character. Quite a character: A terminal arylalumylene complex of platinum was obtained by the reaction of a dialumene-benzene adduct and [Pt(PCy3)2]. Reduction of 1,2-dibromodialumanes in the presence of [Pt(PCy3)2] also afforded the terminal arylalumylene complexes. DFT calculations suggest that the Al-Pt bonds in the arylalumylene complexes have a significantly high electrostatic character.