1644599-55-2Relevant academic research and scientific papers
Synthesis of fully substituted 3-formyl-4-iodofurans via a gold(I)-catalyzed oxidation/1,2-alkynyl migration/cyclization/iodination cascade
Wang, Tao,Shi, Shuai,Rudolph, Matthias,Hashmi, A. Stephen K.
supporting information, p. 2337 - 2342 (2014/07/21)
A highly efficient gold(I)-catalyzed cascade reaction for the synthesis of fully substituted 3-formyl-4-iodofurans has been developed. Mechanistic investigations indicate a reaction pathway that involves a direct iodination reaction of the organogold intermediate via functionalization of the Au=C(sp2) bond, instead of a direct iodination of the 3-formylfurans.
