164469-92-5

Basic information

• Product Name: ethyl-(1-methylene-3-phenyl-prop-2-ynyl)-ether
• Synonyms: ethyl-(1-methylene-3-phenyl-prop-2-ynyl)-ether
• CAS NO: 164469-92-5
• Molecular Weight: 172.227
• Mol File: 164469-92-5.mol

Chemical Properties

• CAS DataBase Reference: ethyl-(1-methylene-3-phenyl-prop-2-ynyl)-ether(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl-(1-methylene-3-phenyl-prop-2-ynyl)-ether(164469-92-5)
• EPA Substance Registry System: ethyl-(1-methylene-3-phenyl-prop-2-ynyl)-ether(164469-92-5)

Safety Data

• Hazardous Substances Data: 164469-92-5(Hazardous Substances Data)

Upstream product

• 718617-04-0 ethyl-(1-bromomethyl-3-phenyl-prop-2-ynyl)-ether 
• 100704-20-9 1-Bromoethenyl ethyl ether 
• 536-74-3 phenylacetylene 
• 2216-94-6 phenylpropynoic acid ethyl ester 
• 6738-06-3 phenylethynylmagnesium bromide 

Downstream Products

• 1817-57-8 4-phenyl-3-butyne-2-one 
• 7107-21-3 (3-ethoxybutyl)benzene 

Relevant articles and documents

Formation of 1- and 2-Alkoxyenynes in Palladium-Catalyzed Cross-Coupling of 1- and 2-Bromoalkenyl Alkyl Ethers with Alkynes

A preparative route to 1- and 2-alkoxyenynes is developed on the basis of stereoselective cross-coupling of 1- and 2-haloalkenyl alkyl ethers with terminal alkynes in the presence of palladium catalyst. Hydrolysis of 1- and 2-alkoxyenynes yields carbonyl derivatives containing a triple bond: substituted acetaldehyde and ketone, respectively.

METHYLENATIONS OF HETEROATOM-SUBSTITUTED CARBONYLS WITH DIMETHYL TITANOCENE

Reaction of dimethyl titanocene with a variety of heteroatom-substituted carbonyl compounds, including: silylesters, anhydrides, carbonates, amides, imides, thioesters, selenoesters and acyl silanes gives the corresponding heteroatom-substituted alkenes.