1645293-16-8

Basic information

• Product Name: C₂₂H₁₅N₅O₂S
• CAS NO: 1645293-16-8
• Molecular Weight: 413.459
• Mol File: 1645293-16-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₂H₁₅N₅O₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₁₅N₅O₂S(1645293-16-8)
• EPA Substance Registry System: C₂₂H₁₅N₅O₂S(1645293-16-8)

Safety Data

• Hazardous Substances Data: 1645293-16-8(Hazardous Substances Data)

Upstream product

• 670-54-2 ethenetetracarbonitrile 
• 205885-39-8 N-benzyl-N-ethynyl-4-methyl-benzenesulfonamide 

Relevant articles and documents

High-yield formation of substituted tetracyanobutadienes from reaction of ynamides with tetracyanoethylene

A high-yielding sequence of [2+2] cycloaddition-retroelectrocyclization of ynamides with tetracyanoethylene (TCNE) is described. The reaction provided tetracyanobutadiene (TCBD) species, which were characterized by various techniques. DFT and TD-DFT calculations were also performed to complement experimental findings. 2+2=Tetracyanobutadienes: The reaction between ynamides and tetracyanoethylene at room temperature in dichloromethane provides tetracyanobutadienes in good to quantitative yields, following a sequence of [2+2] cycloaddition-retroelectrocyclization (see scheme; EWG=electron- withdrawing group).