16459-19-1Relevant academic research and scientific papers
Catalyst-free intramolecular formal carbon insertion into σ-C-C bonds: A new approach toward phenanthrols and naphthols
Xia, Ying,Qu, Peiyuan,Liu, Zhenxing,Ge, Rui,Xiao, Qing,Zhang, Yan,Wang, Jianbo
supporting information, p. 2543 - 2546 (2013/04/10)
The different reactivity of two kinds of carbonyl groups in keto aldehyde substrates has been exploited for the synthesis of phenanthrols, naphthols, and their heteroatom-containing analogues. Key to this highly efficient and robust methodology is the catalyst-free intramolecular formal diazo carbon insertion of N-tosylhydrazones into keto C-C bonds (see scheme). Copyright
