164669-65-2Relevant academic research and scientific papers
Bromination of Molybdenum Carbonyls revisited: Oxo Complexes and Routes toNew Materials Chemistry
Backhouse, James R.,Lowe, Helen M.,Sinn, Ekkehard,Suzuki, Shigeru,Woodward, Simon
, p. 1489 - 1496 (2007/10/02)
The use of in situ 2> led to considerably improved preparations of for which the rate of decarbonylation to is greatly increased by refluxing under reduced pressure (15-20 mmHg).Attempts to prepare 2> by Br2 addition to cis- or trans-2> led to .The OP(C6H11)3 complex may be used as a catalyst for the epoxidation of cyclohexene or for the addition of singlet oxygen to α-terpinene (1-isopropyl-4-methylcyclohexa-1,3-diene).The species > was adsorbed onto sodium montmorillonite in a new type of reaction for sodium montmorillonite involving multiple abstractions of NaBr from the complex anion.In solution > also decomposes to crystalline 2> which is monoclinic, space group C2/c .
