164729-64-0Relevant academic research and scientific papers
Vibrational spectroscopic studies and ab initio calculations of 2-cyanophenylisocyanid dichloride
Varghese, Hema Tresa,Panicker, C. Yohannan,Philip, Daizy,Pazdera, Pavel
, p. 1055 - 1059 (2007)
FT-Raman and FT-IR spectra of 2-cyanophenylisocyanid dichloride were recorded and analyzed. The vibrational frequencies of the title compound have been computed using the Hartree-Fock/6-31G* basis and compared with the experimental values. The
Synthesis of N-(2-cyanophenyl)chloromethanimidoyl chloride
Pazdera, Pavel,Divisova, Hana,Havlisova, Helena,Borek, Petr
, p. 189 - 194 (2000)
N-(2-Cyanophenyl)chloromethanimidoyl chloride (3) was prepared from 2-isothiocyanatobenzonitrile by the reaction with sulfuryl chloride or gaseous chlorine in an inert solvent. It was found that N-(2-cyanophenyl) chloromethanimidothioic chloride (2) and bis[N-(cyanophenyl)chloromethanimidoyl] sulfide (7) are intermediates of this reaction. The chloride 3 was obtained also by a three-component one-pot reaction of N-(2-cyanophenyl)-formamide in the present of thionyl chloride and sulfuryl chloride. (2-Cyanophenyl)-(1-{[(2- cyanophenyl)-imino]methoxy}methylidene)ammonium chloride (6) was detected as a by-product of this reaction. Identity of all reaction products was confirmed by GC-MS, FTIR, 1H and 13C NMR spectroscopy.
