1648802-66-7Relevant academic research and scientific papers
Efficient synthesis of eight-membered nitrogen heterocycles from O-propargylic oximes by rhodium-catalyzed cascade reactions
Nakamura, Itaru,Sato, Yoshinori,Takeda, Keisuke,Terada, Masahiro
, p. 10214 - 10219 (2014)
Azocine derivatives were successfully synthesized from O-propargylic oximes by means of a Rh-catalyzed 2,3-rearrangement/heterocyclization cascade reaction. Moreover, the chirality of the substrate was maintained throughout the cascade process to afford the corresponding optically active azocines.
