1649-73-6

Basic information

• Product Name: Octadecane, 1-fluoro-
• CAS NO: 1649-73-6
• Molecular Formula: C18H37F
• Molecular Weight: 272.49
• Mol File: 1649-73-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Octadecane, 1-fluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Octadecane, 1-fluoro-(1649-73-6)
• EPA Substance Registry System: Octadecane, 1-fluoro-(1649-73-6)

Safety Data

• Hazardous Substances Data: 1649-73-6(Hazardous Substances Data)

Upstream product

• 629-93-6 n-iodooctadecane 
• 112-89-0 1-Bromooctadecane 
• 112-04-9 octadecyltrichlorosilane 

Relevant articles and documents

Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization

We report a contra-thermodynamic isomerization of internal olefins to terminal olefins driven by redox reactions and formation of Si-F bonds. This process involves chain-walking hydrosilylation of internal olefins and subsequent formal retro-hydrosilylation. The process rests upon the high activities of platinum hydrosilylation catalysts for isomerization of metal alkyl intermediates and a new, metal-free process for the conversion of alkylsilanes to alkenes. By this approach, 1,2-disubstituted and trisubstituted olefins are converted to terminal olefins.

TETRABUTYLAMMONIUM BIFLUORIDE: A VERSATILE AND EFFICIENT FLUORINATING AGENT

The use of tetrabutylammonium bifluoride as stable and easily available source of fluoride ion in nucleophilic substitution processes with different substrates is reported.