165199-19-9

Upstream product

• 938060-73-2 C₆₈H₇₂INO₁₃SSi 
• 938060-82-3 methyl 4,6-O-benzylidene-3-O-tert-butyldiphenylsilyl-2-O-(2-iodo-1-(p-methoxyphenyl 3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosid-4-O-yl)prop-2-enyl)-1-thio-α-D-mannopyranoside 
• 938060-78-7 methyl 4,6-O-benzylidene-2-O-(prop-2-ynyl)-3-O-tert-butyldiphenylsilyl-1-thio-α-D-mannopyranoside 
• 938060-80-1 methyl 4,6-O-benzylidene-2-O-(allenyl)-3-O-tert-butyldiphenylsilyl-1-thio-α-D-mannopyranoside 
• 129575-89-9 p-methoxyphenyl 3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 

Downstream Products

• 938060-83-4 p-methoxyphenyl 4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 165290-38-0 p-methoxyphenyl O-(2-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->3)-O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 
• 904690-09-1 p-methoxyphenyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1->3)-2-O-acetyl-β-D-mannopyranosyl-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside 

Relevant academic research and scientific papers

Propargyl mediated intramolecular aglycon delivery (IAD): applications to the synthesis of core N-glycan oligosaccharides

The use of propargyl mediated intramolecular aglycon delivery (IAD) for the synthesis of the key Manβ(1→4)GlcNAc linkage of N-glycan oligosaccharides, including the core N-glycan pentasaccharide, is investigated. Isomerisation of a 2-O-progargyl group of

β-Mannosylation of N-acetyl glucosamine by propargyl mediated intramolecular aglycon delivery (IAD): synthesis of the N-glycan core pentasaccharide

An efficient and completely stereocontrolled synthesis of the N-glycan Manβ(1-4)GlcNAc disaccharide is achieved by propargyl mediated intramolecular aglycon delivery (IAD). Isomerisation of the 2-O-progargyl group of a manno thioglycoside to an allene is