165272-07-1Relevant academic research and scientific papers
Reactivity of niobocene dihalogenides toward nitroso derivatives. EPR and IR characterization of the first niobium(IV) complexes containing an ArNO-N,O ligand
Lucas, D.,Mugnier, Y.,Antinolo, A.,Otero, A.,Garcia-Yuste, S.,Fajardo, M.
, p. 7 - 10 (1995)
The reaction of 5-C5H4R)2X2> tBu, X = Cl> with nitroso derivatives ArNO : Ar = Ph; b: Ar = o-CH3-C6H4; c: Ar = p-(CH3)2NC6H4> yields paramagnetic complexes formulated as 5-C5H4R)(η3-C5H4R)X2(ArNO-N,O) 1a, 1b, 1c, 2a, 3a, 4a nad 4c, which have been characterized by ESR and IR spectroscopy. Keywords: Niobium; Nitrosobenzene complexes; EPR; Electrochemistry
