1654742-10-5Relevant academic research and scientific papers
Thiocarbamate-Directed Tandem Olefination-Intramolecular Sulfuration of Two Ortho C-H Bonds: Application to Synthesis of a COX-2 Inhibitor
Li, Wendong,Zhao, Yingwei,Mai, Shaoyu,Song, Qiuling
supporting information, p. 1162 - 1166 (2018/02/23)
A palladium-catalyzed dual ortho C-H bond activation of aryl thiocarbamates is developed. This tandem reaction initiates by thiocarbamate-directed ortho C-H palladation, which leads to favorable olefin insertion rather than reductive elimination. The oxid
Palladium-catalyzed intramolecular oxidative C-H sulfuration of aryl thiocarbamates
Zhao, Yingwei,Xie, Yinjun,Xia, Chungu,Huang, Hanmin
supporting information, p. 2471 - 2476 (2014/09/17)
A palladium-catalyzed intramolecular C-H bond sulfuration reaction of aryl thiocarbamates has been developed. This strategy provides a new route to benzo[d][1,3]oxathiol-2-ones with tolerance of a wide range of substituents. Mechanistic studies suggested
