165524-85-6Relevant articles and documents
Organoboron-catalyzed regio- and stereoselective formation of β-2-deoxyglycosidic linkages
Beale, Thomas M.,Moon, Patrick J.,Taylor, Mark S.
supporting information, p. 3604 - 3607 (2014/07/21)
A borinic acid derived catalyst enables regioselective and β-selective reactions of 2-deoxy- and 2,6-dideoxyglycosyl chloride donors with pyranoside-derived acceptors having unprotected cis-1,2- and 1,3-diol groups. The use of catalysis to promote a β-sel
Regio- and stereoselectivity of the addition of O-, S-, N-, and C-nucleophiles to the β vinyl oxirane derived from D-glucal
Di Bussolo, Valeria,Caselli, Micaela,Romano, Maria Rosaria,Pineschi, Mauro,Crotti, Paolo
, p. 8702 - 8708 (2007/10/03)
6-O-Trityl- (1a) and 6-(O-benzyl)-substituted epoxide (1b) derived from D-glucal were examined in their addition reactions with O-, C-, N-, and S-nucleophiles. A 1,4-regio- and β-stereoselective or an anti 1,2-addition pathway is commonly observed dependi
Strategy in oligosaccharide synthesis: An application to a concise total synthesis of the KH-1(adenocarcinoma) Antigen
Deshpande, Prashant P.,Kim, Hyunjin M.,Zatorski, Andrzej,Park, Tae-Kyo,Ragupathi, Govindaswami,Livingston, Philip O.,Live, David,Danishefsky, Samuel J.
, p. 1600 - 1614 (2007/10/03)
A concise and potentially practical synthesis of the title compound has been achieved. The route features a high degree of convergence and economy of synthetic operations. A key step is the concurrent introductory addition of three α-1-fucosyl residues at