165611-33-6

Basic information

• Product Name: methyl (S)-tetrahydrofuran-3-carboxylate
• Synonyms: methyl (S)-tetrahydrofuran-3-carboxylate;(S)-methyl tetrahydro-3-furoate,methyl (3S)-oxolane-3-carboxylate;methyl (3S)-oxolane-3-carboxylate;(S)-Methyl tetrahydrofuran-3-carboxylate
• CAS NO: 165611-33-6
• Molecular Formula: C6H10O3
• Molecular Weight: 130.14
• Mol File: 165611-33-6.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 158.8±23.0 °C(Predicted)
• Appearance: /
• Density: 1.108±0.06 g/cm3(Predicted)
• CAS DataBase Reference: methyl (S)-tetrahydrofuran-3-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (S)-tetrahydrofuran-3-carboxylate(165611-33-6)
• EPA Substance Registry System: methyl (S)-tetrahydrofuran-3-carboxylate(165611-33-6)

Safety Data

• Hazardous Substances Data: 165611-33-6(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 66838-42-4 (3R,S)-tetrahydro-furan-3-carboxylic acid 
• 191347-92-9 (R)-tetrahydrofuran-3-carboxaldehyde 
• 67-56-1 methanol 
• 124391-75-9 3-tetrahydrofuranmethanol 
• 89364-31-8 3-tetrahydrofuroic acid 
• 74-88-4 methyl iodide 
• 865-33-8 potassium methanolate 
• 53750-81-5 4,5-dihydro-furan-3-carboxylic acid methyl ester 

Downstream Products

• 1186609-16-4 5-(tetrahydrofuran-3-yl)-1H-pyrazol-3-amine 
• 124391-75-9 -(+)-3-hydroxymethyltetrahydrofuran 
• 5204-91-1 methyl 5-oxotetrahydro-3-furancarboxylate 

Relevant articles and documents

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Oxidative esterification of alcohols by a single-side organically decorated Anderson-type chrome-based catalyst

The direct esterification of alcohols with non-noble metal-based catalytic systems faces great challenges. Here, we report a new chrome-based catalyst stabilized by a single pentaerythritol decorated Anderson-type polyoxometalate, [N(C4H9)4]3[CrMo6O18(OH)3C{(OCH2)3CH2OH}], which can realize the efficient transformation from alcohols to esters by H2O2oxidation in good yields and high selectivity without extra organic ligands. A variety of alcohols with different functionalities including some natural products and pharmaceutical intermediates are tolerated in this system. The chrome-based catalyst can be recycled several times and still keep the original configuration and catalytic activity. We also propose a reasonable catalytic mechanism and prove the potential for industrial applications.

Conversion of alcohols to alkyl esters and carboxylic acids using heterogeneous palladium-based catalysts

Disclosed are methods for synthesizing an ester or a carboxylic acid from an organic alcohol. To form the ester one reacts, in the presence of oxygen gas, the alcohol with methanol or ethanol. This reaction occurs in the presence of a catalyst comprising palladium and a co-catalyst comprising bismuth, tellurium, lead, cerium, titanium, zinc and/or niobium (most preferably at least bismuth and tellurium). Alternatively that catalyst can be used to generate an acid from that alcohol, when water is also added to the reaction mix.

Asymmetric cross-dimerization between methyl methacrylate and substituted alkene by Ru(0)-bicyclononadiene complex

New Ru(0)-naphthalene complexes containing a bicyclononadiene ligand catalyze the linear cross-dimerization between methyl methacrylate and substituted alkenes by an oxidative coupling mechanism. The chiral (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene complex (S,S)-1b catalyzes asymmetric linear cross-dimerization between methyl methacrylate and 2,5-dihydrofuran to give the cross-dimer in 74% yield in 80% ee.