16582-75-5Relevant academic research and scientific papers
Metal-Free and Visible-Light-Promoted C-3 Thiocyanation of 2-Arylquinolin-4-ones
Chauhan, Parul,Ritu,Preeti,Kumar, Sharvan,Jain, Nidhi
, p. 4334 - 4340 (2019)
A C-3 thiocyanation of 2-aryl-quinolin-4-ones in the presence of eosin-Y and visible light has been developed. The methodology allows easy access to a variety of 2-aryl-3-thiocyano-quinolin-4-ones in moderate to high yields. Regioselective para-thiocyanat
Deltoid versus Rhomboid: Controlling the Shape of Bis-ferrocene Macrocycles by the Bulkiness of the Substituents
Hoffmann, Viktor,Le Pleux, Lo?c,H?ussinger, Daniel,Unke, Oliver T.,Prescimone, Alessandro,Mayor, Marcel
, p. 858 - 866 (2017)
Precise structural control of heteroannularly disubstituted ferrocene (Fc) structures is very challenging as the high rotational mobility of the Fc unit allows a large conformational diversity. Herein we present the syntheses, characterization, and electr
Method for inducing thiocyanation of arylamine compound by visible light
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Paragraph 0042-0045, (2020/08/06)
The invention discloses a method for inducing thiocyanation of an arylamine compound by visible light. Specifically, in the atmosphere of oxygen or air, an arylamine compound, an ammonium thiocyanatecompound and copper chloride dihydrate are added into a
AlCl3-Promoted Thiocyanation of N-Containing Aromatic and Heteroaromatic Compounds Under Solvent-Free Conditions
Nikoofar, Kobra,Gorji, Samareh
, p. 1138 - 1145 (2015/08/04)
Aluminum chloride/Ammonium thiocyanate (AlCl3/NH4SCN) was found to be an effective system for the thiocyanation of some arylamines and indoles to afford the corresponding thiocyanated adducts at room temperature under solvent-free conditions. The efficacy of this combined reagent was also examined in the thiocyanation of pyrrole and isatin. A plausible mechanism of thiocyanation has also been suggested.
Substituted-4-alkylthioalkane-sulfonanilides and operatives
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, (2008/06/13)
Alkane- and monohaloalkane-sulfonanilides substituted in the para position by alkylthio, alkylsulfinyl and alkylsulfonyl groups and additionally substituted by halogen and optionally by trifluoromethyl and agriculturally acceptable salts thereof are useful herbicides.
