165964-51-2Relevant academic research and scientific papers
Reactions of diazo carbonyls with [PtX(CH3)(chiral diphosphine)] (X = Cl, Br, I): Chemoselectivity and diastereoselectivity of Pt-C and Pt-X carbene insertion
Bergamini, Paola,Costa, Emiliana,Orpen, A. Guy,Pringle, Paul G.,Smith, Martin B.
, p. 3178 - 3187 (2008/10/09)
In polar solvents (e.g. MeCN), ethyl diazoacetate reacts with [PtXMe(S,S-diop)], where X - Cl, Br, I, to give the corresponding [PtX(CHMeCO2Et)(S,S-diop)] as a 2:1 mixture of diastereoisomers in high yields. The major diastereoisomer of [PtCl(C
