166184-45-8

Upstream product

• 166184-44-7 (1S,2S,3R)-2-methoxy-6-oxo-3-triethylsiloxycyclohexyl benzoate 
• 19493-09-5 Methylenetriphenylphosphorane 
• 943151-06-2 C₁₃H₂₆O₄Si 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 166184-50-5 Benzoic acid (1S,2R,3R)-3-hydroxy-2-methoxy-6-oxo-cyclohexyl ester 
• 166184-29-8 (1R,2S,5R,6S)-5-benzyloxy-6-methoxycyclohex-3-ene-1,2-diol 
• 157727-69-0 (4S,5S,6S)-4-benzyloxy-6-hydroxy-5-methoxycyclohex-2-enone 
• 166184-43-6 (2S,3R,4R)-2,4-dihydroxy-3-methoxycyclohexanone 
• 994-30-9 triethylsilyl chloride 
• 943151-05-1 C₂₀H₃₀O₄Si 
• 943151-04-0 C₂₀H₃₂O₄Si 
• 943150-92-3 C₂₂H₃₆O₄Si 
• 943151-03-9 C₂₀H₃₂O₄Si 
• 943151-02-8 C₂₀H₃₄O₄Si 

Relevant academic research and scientific papers

Formal total synthesis of ovalcin by carbohydrate approach

A formal total synthesis of ovalcin is described herein starting from readily available sugar ribose with selective zinc-mediated ring-opening reaction and Grubbs olefin metathesis as the key steps. Georg Thieme Verlag Stuttgart.

Total synthesis of (-)-ovalicin and analogues from L-quebrachitol

We describe here the first chiral total synthesis of (-)-ovalicin and the synthesis of several related analogues, from the naturally occuring cyclitol L-quebrachitol.

Total synthesis of (-)-Ovalicine from L-Quebrachitol

The first chiral synthesis of (-)-Ovalicine from commercially available L-Quebrachitol in 16 steps and an overall yield of 3.5% is reported.