16630-06-1Relevant academic research and scientific papers
Cu-Catalyzed Stereoselective Borylation of gem-Difluoroalkenes with B2pin2
Zhang, Juan,Dai, Wenpeng,Liu, Qingyun,Cao, Song
, p. 3283 - 3286 (2017)
A novel and efficient method for the synthesis of (Z)-fluorinated alkenylboronic acid pinacol esters via Cu-catalyzed stereoselective borylation of gem-difluoroalkenes using bis(pinacolato)diboron (B2pin2) as the boron source with the assistance of NaOtBu and Xantphos at room temperature was developed.
Copper-Catalyzed Stereoselective Defluorinative Borylation and Silylation of gem-Difluoroalkenes
Tan, Dong-Hang,Lin,Ji, Wei-Wei,Zeng, Yao-Fu,Fan, Wen-Xin,Li, Qingjiang,Gao, Hui,Wang, Honggen
supporting information, p. 1032 - 1037 (2018/01/27)
The copper-catalyzed stereoselective defluorinative borylation and silylation of gem-difluoroalkenes was developed. The protocol led to the exclusive formation of Z type monofluoroalkenyl borons and silanes in generally good efficiency with broad substrat
