166325-81-1

Upstream product

• 166325-80-0 butyl (2S)-2-{benzyloxycarbonyl[(1R)-(1-phenylethyl)]amino}pent-4-enoate 
• 501-53-1 benzyl chloroformate 
• 104849-30-1 butyl (2S)-2-<(R)-1-phenylethylamino>pent-4-enoate 
• 166325-87-7 butyl (2S,6R,E)-7-benzyloxy-6-methyl-2-[(1R)-(1-phenylethyl)]aminohept-4-enoate 
• 1392437-91-0 butyl (2S,6S,E)-2-{benzyloxycarbonyl[(1R)-(1-phenylethyl)]-amino}-6-(tert-butyldimethylsilyloxy)hept-4-enoate 
• 67321-49-7 C₁₄H₁₉NO₂ 

Downstream Products

• 166325-82-2 (3S)-3-{N-benzyloxycarbonyl[(1R)-1-(phenylethyl)]amino}butyrolactone 

Relevant academic research and scientific papers

Remote stereocontrol in reactions between 4- and 5-alkoxyalk-2- enylstannanes and 1-alkoxycarbonylimines and analogues: Stereoselective approaches to novel α-amino acids

Reactions of the allyltin trichloride 45 generated from (4S)-4-benzyloxypent-2-enyl(tributyl)stannane 1 with imines prepared from glyoxylates proceed with useful levels of 1,5-stereocontrol in favour of (4E)-2,6-anti-2-(alkylamino)-6-benzyloxyhept-4-enoat

Remote Asymmetric Induction in Reactions between 4- and 5-Benzyloxypent-2-enyl(tributyl)stannanes and Chiral Imines prepared from Butyl Glyoxylate

Transmetallation of 4- and 5-benzyloxypent-2-enyl(tributyl)stannanes 13 and 18 with tin(IV) chloride generates intermediate allyltin trichlorides which react with imines 9 and ent-9, prepared from butyl glyoxylate and either (R)- or (S)-1-phenylethylamine