166331-78-8Relevant academic research and scientific papers
Electrochemical Fluorination of (Arylthio)methyl Carboxylates and γ-Phenylthio-γ-butyrolactone Derivative
Ito, Satoshi,Kondo, Kaori,Ishii, Hideki,Inagi, Shinsuke,Fuchigami, Toshio
, (2021/07/09)
Electrochemical fluorination of various (arylthio)methyl carboxylates was carried out in aprotic organic solvents containing poly(HF) salts to provide the corresponding O-fluoromethyl carboxylates in good to moderate yield. Electrochemical fluorination of a cyclic analogue, a γ-phenylthio-γ-butyrolactone derivative was also achieved under ultrasonication to give the corresponding 4-fluorinated product in moderate yield.
O-Fluoromethyl Carboxylates and O-Fluoromethyl Carbamates
Schlosser, Manfred,Limat, Dominique
, p. 5807 - 5812 (2007/10/02)
The fluoride catalyzed reaction between acyl fluorides and monomeric formaldehyde affords fluoromethyl carboxylates in acceptable yields. - Fluoromethyl fluoroformate, readily accessible from the corresponding dichloro compound, condenses with amines to give fluoromethyl carbamates.
