166384-49-2Relevant academic research and scientific papers
SOLVOLYSIS OF 3-SUBSTITUTED 4-HOMOADAMANTYL METHANESULPHONATES. CAN THE β-SUBSTITUENT EFFECT DISTINGUISH BETWEEN CLASSICAL AND NON-CLASSICAL ION INTERMEDIATES ?
Okazaki, Takao,Kitagawa, Toshikazu,Takeuchi, Ken'Ichi
, p. 485 - 494 (2007/10/02)
The rates of the solvolysis of 3-R-4-homoadamantyl methanesulphonates (mesylates) (3) were determined in 80percent aqueous ethanol.The relative first-order rate constants at 25 deg C were 1.0 (R=H), 2.29 (R=Ph), 3.26 (R=p-anisyl), 73.6 (R=Me) and 209 (R=E
