166532-24-7

Basic information

• Product Name: (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(V)
• CAS NO: 166532-24-7
• Molecular Weight: 477.643
• Mol File: 166532-24-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(V)(CAS DataBase Reference)
• NIST Chemistry Reference: (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(V)(166532-24-7)
• EPA Substance Registry System: (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(V)(166532-24-7)

Safety Data

• Hazardous Substances Data: 166532-24-7(Hazardous Substances Data)

Upstream product

• 696-63-9 4-Methoxybenzenethiol 
• 163231-16-1 N(C₂H₅)3CH₂C₆H₅⁽¹⁺⁾*ReOCl₄^(1-)=[N(C₂H₅)3CH₂C₆H₅][ReOCl₄] 
• 2150-02-9 bis(2-mercaptoethyl)ether 

Relevant articles and documents

Neutral Oxorhenium(V) Complexes with Tridentate Dithiolates and Monodentate Alkane- or Arene-thiolate Coligands

Oxorhenium(V) complexes (where HSXSH = 3-thia- or 3-oxa-pentane-1,5-dithiol and RSH = alkane- or arene-thiol) have been synthesized by a ligand exchange reaction of with a mixture of HSXSH and RSH in methanol-acetonitrile.The compounds were purified by column chromatography or preparative TLC and characterized by elemental analysis, infrared and 1H NMR spectroscopy.The structure of (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(V) has been determined by X-ray crystallography.The co-ordination is square-pyramidal with the Re atom displaced from the basal plane by 0.728 Angstroem.Co-ordination of the ether group is indicated by the short Re-O(ether) bond distance of 2.103 Angstroem.