16654-64-1Relevant articles and documents
Penta-co-ordinate Silicon: Intramolecular Coordination of O-Fluorosilyl Derivatives of N,N-Disubstituted Aminoethanols and of N-Fluorosilyl Substituted Derivatives of Trimethylethylenediamine
Krebs, Roland,Schomburg, Dietmar,Schmutzler, Reinhard
, p. 282 - 287 (2007/10/02)
Tetrafluorosilane and phenyltrifluorosilane react with the O-trimethylsilyl derivatives of N,N-disubstituted aminoethanols and with the N-trimethylsilyl derivative of N,N,N'-trimethylethylene diamine to give the corresponding monosubstituted fluorosilyl compounds in which, on the basis of 19F NMR spectroscopic studies, intramolecular N-Si bonding raises the coordination number of silicon from four to five (i.e. λ4Si --> λ5Si).The low temperature 19F NMR data suggest a trigonal-bipyramidal configuration at λ5Si with an axial N-Si coordinate bond. - Key words: Penta -Coordinate Silicon, Solution Structure, 19F NMR Spectra