166540-14-3

Basic information

• Product Name: trans-5-chloro-2-phenyladamantan-2-ol
• CAS NO: 166540-14-3
• Molecular Weight: 262.779
• Mol File: 166540-14-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-5-chloro-2-phenyladamantan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: trans-5-chloro-2-phenyladamantan-2-ol(166540-14-3)
• EPA Substance Registry System: trans-5-chloro-2-phenyladamantan-2-ol(166540-14-3)

Safety Data

• Hazardous Substances Data: 166540-14-3(Hazardous Substances Data)

Upstream product

• 20098-17-3 5-chloroadamantan-2-one 
• 591-51-5 phenyllithium 

Downstream Products

• 29480-18-0 2-phenyladamantan-2-ol 

Relevant articles and documents

Stereochemistry of 2-Methyl- and 2-Phenyl-2-adamantyl Cations

When both diastereomers of -2-methyl-2-adamantyl 2,4-dinitrophenolate (18a) and -2-phenyl-2-adamantyl 2,4-dinitrophenolate (18b) were solvolyzed in 40percent aqueous acetone, 1:1 mixtures of (E)- and (Z)--2-R-adamantan-2-ols (19a, b) were obtained.The stereoselectivity of secondary 2-adamantyl cations, attributed to ? participation, is effectively suppressed by charge-stabilizing groups at C-2. - Key Words: Solvolysis / ? Participation / 5-D-2-Adamantyl derivatives