16665-10-4

Basic information

• Product Name: (2R,4R)-4-methyl-2-(2-methylpropyl)tetrahydro-2H-pyran
• Synonyms: (2R,4R)-2-Isobutyl-4-methyltetrahydro-2H-pyran; 2H-pyran, tetrahydro-4-methyl-2-(2-methylpropyl)-, (2R,4R)-
• CAS NO: 16665-10-4
• Molecular Formula: C₁₀H₂₀O
• Molecular Weight: 156.2652
• Mol File: 16665-10-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 181.957°C at 760 mmHg
• Flash Point: 56.522°C
• Density: 0.829g/cm³
• Vapor Pressure: 1.13mmHg at 25°C
• Refractive Index: 1.422
• CAS DataBase Reference: (2R,4R)-4-methyl-2-(2-methylpropyl)tetrahydro-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4R)-4-methyl-2-(2-methylpropyl)tetrahydro-2H-pyran(16665-10-4)
• EPA Substance Registry System: (2R,4R)-4-methyl-2-(2-methylpropyl)tetrahydro-2H-pyran(16665-10-4)

Safety Data

• Hazardous Substances Data: 16665-10-4(Hazardous Substances Data)

Upstream product

• 82684-31-9 cis-erythro-tetrahydroelsholtziol 
• 488-05-1 3-methyl-1-(3-methylfuran-2-yl)butan-1-one 
• 16891-23-9 2-isobutyl-4-methyl-5,6-dihydro-4H-pyran 
• 82684-26-2 3-methyl-1-(3-methyl-2-furyl)-1-butanol 

Relevant articles and documents

A Novel Synthesis of cis-Dihydro-rose Oxide and Related Stereochemistry

A new synthesis of cis-dihydro-rose oxide from elsholtzia oil is presented.The stereochemistry of catalytic hydrogenation of elsholtziol is discussed, and configurations of the diastereoisomers of the resulting tetrahydroelsholtziol have been deduced with the aid of gas chromatography, infrared spectroscopic analysis and conformational analysis.Stereochemical study of catalytic dehydration of tetrahydroelsholtziols indicates that the dehydration-rearrangement reactions follow a trans-elimination process.