166672-28-2Relevant academic research and scientific papers
The phenylthiocyclopropylsilyl group: A useful latent hydroxy group
Angelaud, Rémy,Landais, Yannick
, p. 2025 - 2036 (2007/10/03)
The α-dimethyl(1-phenylthio)cyclopropylsilyl group was used as a new masked hydroxy group. Three procedures have been devised to allow the oxidation of this silicon group in the presence of various functionalities. The desired alcohols are obtained in high yields with retention of configuration at the carbon centre. (C) 2000 Elsevier Science Ltd.
The dimethyl(1-phenylthio)cyclopropylsilyl group as a masked hydroxyl group
Angelaud, Remy
, p. 3861 - 3864 (2007/10/02)
The title group has been used as a masked hydroxyl group, allowing a mild and high yielding oxidation of the C-Si bond. Its use in various transformations demonstrates its chemical stability as well as its ability to be transformed into the corresponding OH group even in the presence of sensitive functionalities.
