166877-98-1Relevant academic research and scientific papers
Synthesis and Silica Gel-catalysed Decomposition of 3-(1-Arylcycloalkyl)-substituted 1,2,4-Trioxolanes and 1,2,4-Dioxazolidines
Fukagawa, Ryoichi,Nojima, Masatomo
, p. 2449 - 2454 (2007/10/02)
Decomposition of 3-(1-phenylcyclopentyl)- and 3-(1-phenylcyclohexyl)-4-benzyl-5-phenyl-1,2,4-dioxazolidines, derived from cycloadditions of benzaldehyde O-oxide and imines, by silica gel mixtures of the corresponding phenylcycloalkene, benzaldehyde, and N-benzylformamide.In the case of 3-(1-arylcyclopentyl)- and 3-(1-phenylcyclohexyl)-substituted 1,2,4-trioxolanes also, a similar mode of decomposition was observed.A mechanism involving heterolytic fission of the C-C bond between the peroxide ring and the cycloalkyl substituent, is proposed.
