167076-41-7

Basic information

• Product Name: [Pd2Me2(μ-S(t)Bu)2(PPh3)2]
• CAS NO: 167076-41-7
• Molecular Weight: 945.854
• Mol File: 167076-41-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd2Me2(μ-S(t)Bu)2(PPh3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd2Me2(μ-S(t)Bu)2(PPh3)2](167076-41-7)
• EPA Substance Registry System: [Pd2Me2(μ-S(t)Bu)2(PPh3)2](167076-41-7)

Safety Data

• Hazardous Substances Data: 167076-41-7(Hazardous Substances Data)

Upstream product

• 289634-43-1 Pd2(CH3)2(μ-Cl)2(PPh3)2 
• 32812-86-5 Pb(S-t-C₄H₉)2 

Downstream Products

• 213540-30-8 ((C₆H₅)2PCH₂(C₁₈H₁₀)CH₂P(C₆H₅)2)Pd(SC(CH₃)3)(CH₃) 

Relevant articles and documents

Synthesis and characterization of dimeric organochalcogenido-bridged methylpalladium and allylpalladium complexes

Dimeric organochalcogenido-bridged methylpalladium and allylpalladium complexes of the types and 3-allyl)2> (E = S or Se; R = Et, iPr, tBu, Ph, C6H4CH3-4, C6H4Cl-4) have been synthesized and characterized by elemental analyses and nuclear magnetic resonance (1H, 13C and 31P) spectroscopy.The methylpalladium complexes exist either as cis isomers or as a mixture of cis and trans forms, with the former predominating.The allylpalladium complexes exist in syn and anti forms.The dynamic behaviour in these complexes was studied by variable-temperature 1H NMR spectroscopy.A few reactions of 3-allyl)2> with free thiols were also investigated.Keywords: Palladium; Allylpalladium; Methylpalladium; Dimeric; Organochalcogenide; NMR