167083-92-3

Upstream product

• 5927-18-4 trimethyl phosphonoacetate 
• 167083-89-8 (4R,5S)-2,2-Dimethyl-5-((2S,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-[1,3]dioxolane-4-carboxylic acid methyl ester 
• 756-79-6 dimethyl methane phosphonate 
• 128478-99-9 methylphosphonic acid dimethyl ester; deprotonated form 
• 125287-98-1 methyl [methyl 2,3,4-tri-O-benzyl-L-threo-β-D-gluco-octopyranosid]uronate 

Relevant academic research and scientific papers

Reaction of sugar phosphonates with sucrose aldehydes. Synthesis of higher analogs of sucrose

The Horner-Emmons reaction between sugar phosphonates Sug-C(O)CH2 P(O)(OMe)2 and aldehydes derived from sucrose afforded precursors of higher analogs of the general formula Sug-C(O)CH=CH-Suc. An example of the functionalization of th

Application of stabilized sugar-derived phosphoranes in the synthesis of higher carbon monosaccharides. First synthesis of a C21-dialdose

C21 Monosaccharide precursors 11 and 12 were synthesized by a coupling of a C12 aldehyde 1 with C9 stabilized phosphoranes 2 and 3 respectively. The 'smaller' C19 sugar 13 was prepared from a C12 alde

Synthesis of derivatives of C19 and C21 dialdoses

C12-monosaccharide derivative 2 (obtained from C12-dialdose 1 in 49% overall yield) was used as the starting material for the preparation of C19- and C21-monosaccharide derivatives. Coupling of aldehyde 3 (prepa