167107-99-5

Upstream product

• 3366-47-0 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabinohex-1-enopyranose 
• 175550-09-1 Acetic acid (2S,5R,6R)-5-hydroxy-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 175673-11-7 Acetic acid (2S,5R,6S)-5-hydroxy-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester 
• 175673-14-0 (2S,3R,6S)-2-((Z)-2-Benzenesulfonyl-2-triethylsilanyl-vinyl)-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-trimethylsilanyloxy-3,6-dihydro-2H-pyran 
• 175673-13-9 (2S,3R,6S)-2-((Z)-2-Benzenesulfonyl-2-triethylsilanyl-vinyl)-6-(tert-butyl-diphenyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-ol 
• 175550-12-6 (2S,3R,6S)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-3,6-dihydro-2H-pyran-3-ol 
• 175673-12-8 Acetic acid (2S,5R,6S)-5-hydroxy-6-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-5,6-dihydro-2H-pyran-2-ylmethyl ester 
• 175550-11-5 (2S,3R,6S)-6-Hydroxymethyl-2-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-3,6-dihydro-2H-pyran-3-ol 
• 167257-12-7 Acetic acid (2S,5R,6S)-5-(tert-butyl-diphenyl-silanyloxy)-6-phenylsulfanylethynyl-5,6-dihydro-2H-pyran-2-ylmethyl ester 

Relevant academic research and scientific papers

Pseudoenantiomeric heteroconjugate addition approach for synthesis of spiro segment of tautomycin

A new synthetic method providing both enantiomers by heteroconjugate addition strategy is described for stereocontrolled synthesis of optically active compounds from D-sugar chirons. Preparation includes introduction of phenylthioacetylene, acidic epimeri

Heteroconjugate Addition at C-1 Position of Pyranose Derivative, Pseudoenantiomeric Methodology for Asymmetric Introdution

A new synthetic method providing both enentiomers by heteroconjugate addition strategy is described for stereocontrolled synthesis of optically active compounds from sugar chirons.Preparation includes introduction of phenylthioacetylene, acidic epimerizat