167111-53-7Relevant academic research and scientific papers
Organomercuration of the carbanion derived from (M=Cr, Mo or W). Crystal and molecular structure of >
Hutton, Alan T.,Wewers, Francois P.
, p. C14 - C16 (1995)
The carbanions resulting from the deprotonation by n-BuLi of compounds of the type (M=Cr, Mo or W) are readily organomercurated by RHgCl to give neutral complexes of the type >.The X-ray crystal structure of the complex with M=Cr and R=Me has been determined, and reveals intermolecular C-H...O hydrogen bonding interactions to carbonyl oxygen acceptor atoms and a weak secondary intermolecular interaction between a carbonyl oxygen and the mercury atom.Keywords: Chromium; Molybdenum; Tungsten; Carbonyl; Bis(diphenylphosphino)methane; Carbanions
Synthesis and structure of [M(CO)4{(PPh2)2CHAu(PPh3)}] (M = Cr, Mo, W)
Fernandez, Eduardo J.,Gimeno, Conception M.,Jones, Peter G.,Laguna, Antonio,Laguna, Mario,et al.
, p. 173 - 178 (2008/10/08)
The reaction of diethyl ether solutions of Li[M(CO)4{(PPh2CH] with [AuCl(PPh3)] gives [M(CO)4{(PPh2CHAu(PPh3)}] (M = Cr, Mo, W). The structure of the derivative with M = Mo was determined by single crystal X-ray diffraction at 173 K. Crystals are monoclin
