16718-10-8Relevant academic research and scientific papers
Transition-metal-free C-S bond formation: A facile access to aryl sulfones from sodium sulfinates via arynes
Pandya, Virat G.,Mhaske, Santosh B.
, p. 3836 - 3839 (2014)
Sulfones have been attractive targets for synthetic organic chemists owing to their immense applications in medicinal, material, and synthetic chemistry. In this context, an efficient transition-metal-free process has been demonstrated, wherein a broad range of alkyl/aryl/heteroaryl sodium sulfinates react with varyingly substituted aryne precursors (o-silyl aryl triflates) under mild reaction conditions to afford structurally diverse sulfones in good to excellent yields.
A PROCESS FOR THE SYNTHESIS OF ARYL SULFONES
-
Page/Page column 11; 12; 20, (2015/06/25)
The present patent discloses a novel, efficient and transition-metal-free room temperature single step process for synthesis of aryl sulfones and substituted aryl sulfones starting from aryl substrates.
