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1,2,4,5-Tetrazine, 1,2-dihydro-3,6-bis(methylthio)- is a chemical compound with the molecular formula C4H8N4S2. It is a heterocyclic compound consisting of a tetrazine ring with two hydrogen atoms attached to the 1 and 2 positions, and two methylthio groups (-SCH3) attached to the 3 and 6 positions. 1,2,4,5-Tetrazine, 1,2-dihydro-3,6-bis(methylthio)- is known for its potential applications in various fields, such as pharmaceuticals, agrochemicals, and materials science. Due to its unique structure and properties, it has been studied for its reactivity, stability, and potential use as a building block in the synthesis of more complex molecules. However, it is important to note that the safety and environmental impact of 1,2,4,5-Tetrazine, 1,2-dihydro-3,6-bis(methylthio)- should be carefully considered before its widespread use.

1672-33-9

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1672-33-9 Usage

Structure

Tetrazine derivative with two methylthio groups attached to the 3 and 6 positions

Usage

Organic synthesis for the preparation of various heterocyclic compounds and functional materials

Potential applications

Development of novel pharmaceuticals and agrochemicals

Unique properties

Reactivity and unique chemical properties

Additional applications

Bioconjugation and bioorthogonal chemistry

Importance

Versatile and significant chemical in multiple scientific and industrial disciplines

Check Digit Verification of cas no

The CAS Registry Mumber 1672-33-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,6,7 and 2 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1672-33:
(6*1)+(5*6)+(4*7)+(3*2)+(2*3)+(1*3)=79
79 % 10 = 9
So 1672-33-9 is a valid CAS Registry Number.

1672-33-9Relevant academic research and scientific papers

Spontaneous resolution of a triple-stranded dinickel(II) helicate generated via intermolecular transamination reaction of S-methylisothiocarbohydrazide in the presence of Ni2+

Dobrov, Anatoly,Arion, Vladimir B.,Shova, Sergiu,Roller, Alexander,Rentschler, Eva,Keppler, Bernhard K.

, p. 4140 - 4145 (2008)

The reaction of S-methylisothiocarbohydrazide hydroiodide [H 2NNHC(SCH3)NNH2·HI] with NiCl 2·6H2O in water at room temperature yielded a triple-stranded dinickel(II) helicate [NiII(L1-L 1)3NiII]I4·4H2O (14+·4I-·4H2O), where L 1-L1 = H2NNHC(SCH3)NNC(SCH 3)NHNH2, in 35% yield, which spontaneously separates in enantiomers upon crystallization. The enantiomers do not racemize at room temperature, even not after 15 h of heating at 90 °C. X-ray diffraction structures of both enantiomers, chiroptical and magnetic properties of 1 4+·4I-·4H2O are reported. Demetallation of the complex by treatment with S2- resulted in 3,6-bis(methylthio)-1,4-dihydro-1,2,4,5-tetrazine (2). Compound 2 undergoes 2-e- oxidation in air to give the known 3,6-bis(methylthio)-1,2,4,5- tetrazine (3). Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

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