16723-48-1Relevant academic research and scientific papers
Reductions of C=O and C=N groups with the systems composed of (η5-C5H5)2MoH2 and acids
Minato, Makoto,Fujiwara, Yutaka,Koga, Miho,Matsumoto, Naoya,Kurishima, Susumu,Natori, Makoto,Sekizuka, Norihiro,Yoshioka, Ken-Ichiro,Ito, Takashi
, p. 139 - 145 (1998)
Selective reductions of organic compounds, such as carbonyl compounds and imines, using a system composed of Cp2MoH2 and acids are examined. This system can reduce the substrates under mild conditions. Extremely high diastereoselectivity was achieved in the reduction of 4-t-butylcyclohexanone. The reactivity of imines depends on their structure. Aromatic imines are found to be more reactive than aliphatic imines.
Sterically-controlled regioselective para-substitutions of aniline
Dyer, Philip W.,Fawcett, John,Griffith, Gerald A.,Hanton, Martin J.,Olivier, Celine,Patterson, Adam R.,Suhard, Samuel
, p. 3835 - 3837 (2007/10/03)
Introduction of statically demanding 1-isopropyl-2-methyl-propyl or triisopropylsilyl groups at the nitrogen of aniline allows high-yielding regioselective para-substitution to be achieved using a lithiation/substitution sequence. The Royal Society of Che
