167282-22-6

Basic information

• Product Name: Butanal, 3-(dimethylphenylsilyl)-
• CAS NO: 167282-22-6
• Molecular Formula: C12H18OSi
• Molecular Weight: 206.36
• Mol File: 167282-22-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Butanal, 3-(dimethylphenylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Butanal, 3-(dimethylphenylsilyl)-(167282-22-6)
• EPA Substance Registry System: Butanal, 3-(dimethylphenylsilyl)-(167282-22-6)

Safety Data

• Hazardous Substances Data: 167282-22-6(Hazardous Substances Data)

Upstream product

• 123-73-9 trans-Crotonaldehyde 
• 768-33-2 phenyldimethylsilyl chloride 
• 3839-31-4 dimethyl(phenyl)silyl lithium 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 123-73-9 crotonaldehyde 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 67473-43-2 3-(dimethyl(phenyl)silyl)butanoic acid ethyl ester 

Downstream Products

• 120196-04-5 (2RS,4SR)-4-dimethyl(phenyl)silylpentan-2-ol 
• 120196-04-5 (2RS,4RS)-4-dimethyl(phenyl)silylpentan-2-ol 
• 191916-88-8 (Z)-5-(Dimethyl-phenyl-silanyl)-hex-2-enoic acid methyl ester 
• 191916-72-0 (E)-5-(Dimethyl-phenyl-silanyl)-hex-2-enoic acid methyl ester 
• 1283095-90-8 (R)-2-((R)-1-(dimethyl(phenyl)silyl)ethyl)-4,4-bis(phenylsulfonyl)butanal 
• 454-57-9 fluorodimethylphenylsilane 

Relevant articles and documents

CuI-catalyzed conjugate addition of silyl boronic esters: Retracing catalytic cycles using isolated copper and boron enolate intermediates

Copper(I)-catalyzed conjugate additions of silyl boronic esters to α,β-unsaturated aldehydes, ketones, and esters are synthetically well-established reactions. For the first time central reactive intermediates as well as the boron enolates as the primary

Copper(II)-catalyzed silyl conjugate addition to α,β-unsaturated conjugated compounds: Bronsted base-assisted activation of Si-b bond in water

A mild method for the installation of the dimethylphenylsilyl group on the β-carbon of electron-deficient olefins is reported. In the presence of a catalytic amount of copper(II) (1 mol %) and amine base (5 mol %) at rt, the transformation proceeds effici

Conjugate additions of a simple monosilylcopper reagent with use of the CuI-DMS complex: Stereoselectivities and a dramatic impact by DMS

(Chemical Equation Presented) Conjugate additions utilizing the simple monosilylcuprate reagent Li[PhMe2SiCuI] to α,β-unsaturated carbonyl compounds are described. The presence of dimethyl sulfide (DMS), either as a component originating from t