167301-17-9Relevant academic research and scientific papers
Mechanistic analysis of double hydrogen dyotropy in syn-sesquinorbornene disulfones. A combined kinetic and theoretical evaluation of primary deuterium isotope effects
Houk,Li, Yi,McAllister, Michael A.,O'Doherty, George,Paquette, Leo A.,Siebrand, Willem,Smedarchina, Zorka K.
, p. 10895 - 10913 (2007/10/02)
Two sets of syn-sesquinorbornene disulfones have been prepared that carry either one or two deuterium atoms α to the sulfonyl substituents. The rates of dyotropic rearrangement were measured in these systems in order to assess the deuterium isotope effect
