167320-32-3

Upstream product

• 712-50-5 Cyclohexyl phenyl ketone 
• 17530-09-5 1,2-dicyclohexyl-1,2-diphenyl-ethane-1,2-diol 
• 96071-74-8 1,2-dicyclohexyl-2,2-diphenyl-ethanone 

Downstream Products

• 17530-09-5 1,2-dicyclohexyl-1,2-diphenyl-ethane-1,2-diol 
• 712-50-5 Cyclohexyl phenyl ketone 
• 96071-74-8 1,2-dicyclohexyl-2,2-diphenyl-ethanone 

Relevant academic research and scientific papers

Synthesis of dialkenyl dichalcogenides via alkenechalcogenolate ions generated by treating ketone p-Toluenesulfonylhydrazones with a base and elemental chalcogen

Alkeneselenolate and alkenetellurolate ions were generated by treating ketone p-toluenesulfonylhydrazones possessing an α-methylene or an α-methine group with t-BuOK and elemental selenium or tellurium, respectively, at 110-150°C, and were converted into dialkenyl dichalcogenides by aerobic oxidation.

'High-surface sodium' as a reducing agent for TiCl 3

Sodium deposited on inorganic supports such as Al2O3, TiO2 and NaCl ('high-surface sodium') is a cheap, readily prepared, nonpyrophoric reducing agent for TiCl3. The low-valent titanium thus obtained, after only 1 h reduction time, is well suited for McMurry coupling reactions, particularly of aromatic carbonyl compounds. It exhibits a previously unrivalled template effect for the cyclization of dicarbonyl compounds to (macrocyclic) cycloalkenes and is suitable for the reduction of N-acyl-2-aminobenzophenone derivatives to 2,3-disubstituted indoles. Even a 36-membered ring could be formed without recourse to high dilution techniques.