167394-01-6Relevant academic research and scientific papers
Conformationally rigid diamide complexes: Synthesis and structure of tantalum(III) alkyne derivatives
Guérin, Frédéric,McConville, David H.,Vittal, Jagadese J.
, p. 3154 - 3156 (1995)
The chelating diamide complexes mer-TaCl3(BDPP) (2), mer-TaCl3(BDPP) (3), and (BDPP)Ta(η2-RC≡CR)Cl (4a, R = Pr; 4b, R = Et; 4c, R = Ph) (BDPP = 2,6-(ArNCH2)2-NC5H3; Ar = 2,6-sup
Successive insertion of alkynes into a tantalum-alkynyl bond: Implications for the coordination polymerization of alkynes
Guérin, Frédéric,McConville, David H.,Vittal, Jagadese J.,Yap, Glen A. P.
, p. 1290 - 1296 (2008/10/08)
The reaction of 2,6-[ArN(SiMe3)CH2]2NC5H3 (1, BDPP(SiMe3)2, Ar = 2,6-iPr2C6H3) with TaCl5 yields the complex mer-(BDPP)TaCl
