16741-15-4Relevant academic research and scientific papers
Acyl group migration and cleavage in selectively protected β-D-galactopyranosides as studied by NMR spectroscopy and kinetic calculations
Roslund, Mattias U.,Aitio, Olli,Waerna, Johan,Maaheimo, Hannu,Murzin, Dmitry Yu.,Leino, Reko
supporting information; experimental part, p. 8769 - 8772 (2009/02/03)
The migration of acetyl, pivaloyl, and benzoyl protective groups and their relative stabilities at variable pH for a series of β-D-galactopyranoses were studied by NMR spectroscopy. The clockwise and counterclockwise migration rates for the different este
Selectively protected galactose derivatives for the synthesis of branched oligosaccharides
Lehtil?, Reko L.,Lehtil?, Juho O.,Roslund, Mattias U.,Leino, Reko
, p. 3653 - 3661 (2007/10/03)
Synthesis and characterization of several new anomerically pure galactose derivatives, based on simple and effective protective group manipulations of benzyl β-D-galactopyranoside, are reported. The monosaccharides described contain selectively protected/deprotected hydroxyl functionalities at their 1,2,3,4- and 6-positions rendering them useful as building blocks for construction of branched oligosaccharides.
