16744-22-2Relevant academic research and scientific papers
Direct syn insertion of alkynes and allenes into Au-Si bonds
Joost, Maximilian,Gualco, Pauline,Mallet-Ladeira, Sonia,Amgoune, Abderrahmane,Bourissou, Didier
supporting information, p. 7160 - 7163 (2013/07/26)
Complete control: Alkynes and allenes are shown to insert into Au-Si bonds with complete stereocontrol and in most cases complete regiocontrol. The ensuing β-silyl vinylgold complexes have been characterized by spectroscopic and crystallographic means. Th
(Trimethylphosphine)(triphenylsilyl)gold(I) and related compounds
Oroz, Miguel Monge,Schier, Annette,Schmidbaur, Hubert
, p. 26 - 29 (2007/10/03)
Mononuclear coordination compounds of the type (R3P)AuSiR'3 with R = R' = Ph and R = Me, R' = Ph have been obtained from reactions of the corresponding halide complexes (R3P)AuCl with the silyllithium reagent LiSiPh3
