167646-68-6

Upstream product

• 1866-39-3 trans-p-methylcinnamic acid 
• 20754-20-5 3-p-tolyl-acrylic acid methyl ester 
• 54636-56-5 (E)-1-(3-bromoprop-1-en-1-yl)-4-methylbenzene 
• 128577-66-2 (E)-6-(p-tolyl)hex-5-en-1-ol 
• 693-89-0 1-methylcyclopent-1-ene 
• 101671-00-5 (E)-2-(4-methylphenyl)-1-nitroethene 

Downstream Products

• 1311160-89-0 (3R,3aS,9R,9aS)-7-nitro-3-((S)-2-nitro-1-phenylethyl)-9-(p-tolyl)-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta[b]quinoline 
• 1311160-87-8 (3R,3aS,9R,9aS)-3-((S)-2-nitro-1-phenylethyl)-9-(p-tolyl)-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta[b]quinoline 
• 1311160-88-9 (3R,3aS,9R,9aS)-7-bromo-3-((S)-2-nitro-1-phenylethyl)-9-p-tolyl-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta[b]quinoline 

Relevant academic research and scientific papers

Dealkenylative Alkenylation: Formal σ-Bond Metathesis of Olefins

The dealkenylative alkenylation of alkene C(sp3)?C(sp2) bonds has been an unexplored area for C?C bond formation. Herein 64 examples of β-alkylated styrene derivatives, synthesized through the reactions of readily accessible feedstock olefins with β-nitrostyrenes by ozone/FeII-mediated radical substitutions, are reported. These reactions proceed with good efficiencies and high stereoselectivities under mild reaction conditions and tolerate an array of functional groups. Also demonstrated is the applicability of the strategy through several synthetic transformations of the products, as well as the syntheses of the natural product iso-moracin and the drug (E)-metanicotine.

Asymmetric organocatalytic synthesis of complex cyclopenta[ b ]quinoline derivatives

An efficient one-pot procedure that provides a direct access to polycyclic hexahydrocyclopenta[b]quinoline derivatives having five stereogenic centers has been developed. The system displays great tolerance toward different aldehydes, anilines, and nitroa