16766-55-5Relevant academic research and scientific papers
Synthesis, structure and reactivity of organogold compounds of relevance to homogeneous gold catalysis
Hashmi, A. Stephen K.,Ramamurthi, Tanuja Dondeti,Rominger, Frank
experimental part, p. 592 - 597 (2009/06/05)
Organogold(I) phosphane complexes were prepared, their structure was investigated and their reactivity in reactions with Michael acceptors, sources of electrophilic halogens and protons were investigated.
INTRAMOLECULAR DEUTERIUM ISOTOPE EFFECTS IN THE META PHOTOCYCLOADDITION OF AROMATIC COMPOUNDS TO ALKENES.
Vaal, P. de,Lodder, G.,Cornelisse, J.
, p. 4585 - 4590 (2007/10/02)
The effect of substitution of hydrogen by deuterium in some aromatic compounds on product distributions in the meta photocycloaddition to alkenes was investigated.The isotope effects found are in agreement with a polar mechanism.
An Increment System for Deuterium Isotope Effects on 13C Chemical Shifts of Methylated Benzenes
Berger, Stefan,Diehl, Bernd W. K.
, p. 1073 - 1076 (2007/10/02)
The complete series of all possible benzenes bearing one deuterium atom and one to five methyl groups was synthesized.The deuterium isotope effects on the carbon chemical shifts of the aromatic and aliphatic carbon atoms were measured and shown to obey an empirical increment system.The isotope effects over one bond correlate with the C,H spin coupling constants. KEY WORDS 13C NMR, deuterium isotope effects, methylbenzenes
