16766-64-6

Basic information

• Product Name: 3-phenyltetrahydrothiophene 1,1-dioxide
• Synonyms: 3-Phenyl-tetrahydro-thiophene 1,1-dioxide; thiophene, tetrahydro-3-phenyl-, 1,1-dioxide
• CAS NO: 16766-64-6
• Molecular Formula: C₁₀H₁₂O₂S
• Molecular Weight: 196.2661
• Mol File: 16766-64-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 393.1°C at 760 mmHg
• Flash Point: 249°C
• Density: 1.23g/cm³
• Vapor Pressure: 4.94E-06mmHg at 25°C
• Refractive Index: 1.566
• CAS DataBase Reference: 3-phenyltetrahydrothiophene 1,1-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenyltetrahydrothiophene 1,1-dioxide(16766-64-6)
• EPA Substance Registry System: 3-phenyltetrahydrothiophene 1,1-dioxide(16766-64-6)

Safety Data

• Hazardous Substances Data: 16766-64-6(Hazardous Substances Data)

Upstream product

• 2288-18-8 2-phenyl-1,3-butadiene 
• 57465-40-4 2,5-dihydro-3-phenylthiophene 1,1-dioxide 

Relevant articles and documents

Enantioselective synthesis of chiral sulfones by ir-catalyzed asymmetric hydrogenation: A facile approach to the preparation of chiral allylic and homoallylic compounds

A highly efficient and enantioselective Ir-catalyzed hydrogenation of unsaturated sulfones was developed. Chiral cyclic and acyclic sulfones were produced in excellent enantioselectivities (up to 98% ee). Coupled with the Ramberg-Baecklund rearrangement, this reaction offers a novel route to chiral allylic and homoallylic compounds in excellent enantioselectivities (up to 97% ee) and high yields (up to 94%).