167690-10-0

Basic information

• Product Name: Methyl β-tert-butyl-5-chloro-2-nitrohippurate
• Synonyms: Methyl β-tert-butyl-5-chloro-2-nitrohippurate
• CAS NO: 167690-10-0
• Molecular Weight: 328.752
• Mol File: 167690-10-0.mol

Chemical Properties

• CAS DataBase Reference: Methyl β-tert-butyl-5-chloro-2-nitrohippurate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl β-tert-butyl-5-chloro-2-nitrohippurate(167690-10-0)
• EPA Substance Registry System: Methyl β-tert-butyl-5-chloro-2-nitrohippurate(167690-10-0)

Safety Data

• Hazardous Substances Data: 167690-10-0(Hazardous Substances Data)

Upstream product

• 53386-65-5 N-(t-butyl)glycine methyl ester 
• 41994-44-9 5-chloro-2-nitrobenzoyl chloride 
• 2516-95-2 5-chloro-2-nitrobenzoic acid 

Downstream Products

• 167689-85-2 4-tert-Butyl-7-chloro-1H-1,4-benzodiazepine-2,5-dione 
• 1027935-88-1 [(2-Amino-5-chloro-benzoyl)-tert-butyl-amino]-acetic acid methyl ester 

Relevant articles and documents

Palladium(II)-Mediated Coupling Reactions of Bromo- and Iodo-1H-1,4-benzodiazepine-2,5-diones. A Route to Functionalized Benzodiazepinediones

A series of 7-, 8-, and 9-bromo- and iodo-1,4-benzodiazepine-2,5-diones have been prepared and examined as substrates for palladium(II)-mediated coupling reactions with alkenes, alkynes, arylstannanes, and heteroarylstannanes.The benzodiazepinediones 6a,e,g were prepared from the reaction of o-nitrobenzoyl chlorides 3a-c and methyl tert-butylglycinate followed by nitro reduction and cyclization.Regioselective halogenation gave 6c,d,f.Bromo- and iodobenzodiazepinediones 6c,d,f,g were then converted to alkenyl-, alkynyl-, aryl-, and heteroaryl-substituted benzodiazepinediones in moderate to good yield in the presence of palladium(II).

Methods for controlling undesirable plant species with benzodiazepine compounds

There are provided methods for controlling undesirable plant species with benzodiazepine compounds of formulas I and II STR1 Further provided are herbicidal compositions comprising those compounds.