167690-79-1

Basic information

• Product Name: Benzene, 1-[(S)-[(1E)-1-iodo-1-hexenyl]sulfinyl]-4-methyl-
• CAS NO: 167690-79-1
• Molecular Formula: C13H17IOS
• Molecular Weight: 348.248
• Mol File: 167690-79-1.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(S)-[(1E)-1-iodo-1-hexenyl]sulfinyl]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(S)-[(1E)-1-iodo-1-hexenyl]sulfinyl]-4-methyl-(167690-79-1)
• EPA Substance Registry System: Benzene, 1-[(S)-[(1E)-1-iodo-1-hexenyl]sulfinyl]-4-methyl-(167690-79-1)

Safety Data

• Hazardous Substances Data: 167690-79-1(Hazardous Substances Data)

Upstream product

• 61783-64-0 (+)-(S)-1-hexynyl p-tolyl sulfoxide 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 693-02-7 hex-1-yne 

Downstream Products

• 167690-82-6 1-Methyl-4-[(S)-((Z)-octa-1,3-diene)-3-sulfinyl]-benzene 
• 1045346-15-3 (-)-(R)-3-(Z)-5-(Z)-5-(p-tolylsulfinyl)deca-3,5-dien-1-ol 
• 1045346-16-4 4-(Z)-6-(Z)-5-(p-tolylsulfinyl)undeca-4,6-dien-1-ol 
• 1045346-18-6 (-)-(S)-2-(Z)-4-(Z)-3-methyl-4-(p-tolylsulfinyl)nona-2,4-dien-1-ol 

Relevant articles and documents

Stereocontrolled Synthesis of Enantiomerically Pure 2-Dienyl Sulfoxides via Palladium-Catalyzed Coupling Reactions

Enantiopure 2-sulfinyl dienes can be prepared via regio- and stereoselective hydrostannylation of alkynylsulfoxides; after conversion to the corresponding vinyliodides these substrates may be coupled with vinylstannanes via Stille methodology in the prese

Synthesis of Enantiopure 3-Hydroxypiperidines from Sulfinyl Dienyl Amines by Diastereoselective Intramolecular Cyclization and [2,3]-Sigmatropic Rearrangement

The highly diastereoselective base-promoted intramolecular cyclization of a variety of enantiopure sulfinyl dienyl amines provides novel sulfinyl tetrahydropyridines that are readily converted to 3-hydroxy tetrahydropyridines via sigmatropic rearrangement. The influence of N- and C- substituents on the process has been studied. Procedures to shorten the sequence such as the tandem cyclization followed by [2,3]-sigmatropic rearrangement, as well as cyclization of the free amine, under Boc- or ArSO- deprotection conditions have been examined. Good to excellent levels of selectivity are generally observed for the reported transformations (dr: 75/25 to >98/2). A novel protocol to access substituted amino dienyl sulfoxides is also reported.

Synthesis and diastereoselective complexation of enantiopure sulfinyl dienes: The preparation of sulfinyl iron(0) dienes

The preparation of a diverse array of enantiomerically pure 1- and 2- sulfinyl dienes has been achieved via Stille coupling of halovinyl sulfoxides and vinyl stannanes, hydrogenation of 1-sulfinyl-1-en-3-ynes, or vinylcupration of 1-sulfinyl alkynes. Form